Cyano- and chloro-substituted coronene diimides as solution-processable electron-transporting semiconductors.

نویسندگان

  • Chenhao Zhang
  • Ke Shi
  • Kang Cai
  • Jiajun Xie
  • Ting Lei
  • Qifan Yan
  • Jie-Yu Wang
  • Jian Pei
  • Dahui Zhao
چکیده

3,4,9,10-Tetracyano- and tetrachlorocoronene-1,6,7,12-tetracarboxy diimides with low LUMO levels at -3.9 to -4.2 eV are developed. These molecules manifest potent n-type semiconductive capability in solution-processed field-effect transistors, with electron mobilities of up to 0.16 cm(2) V(-1) s(-1) measured in air. The device performances of analogous molecules elucidate the importance of side chain structures in the semiconductive properties.

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عنوان ژورنال:
  • Chemical communications

دوره 51 33  شماره 

صفحات  -

تاریخ انتشار 2015